I joined eHarmoney back in September and I really like it.
The site matches you with people based on if they are compatible with you in regards to your personality profile. Personally, I received many matches (it got up to over 60 people).
About the guided communication... you send and receive multiple choice questions with a match after checking out their profile, and then you ask and answer short answer questions, and eventually you send emails through eharmoney.com
Then, with my case, we exchanged AIM screennames... then exchanged phone numbers... then actually met.
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